Shape-resonance-enhanced vibrational effects in the angular distributions of C 1s photoelectrons from fixed-in-space CO molecules

Phys Rev Lett. 2003 Oct 17;91(16):163001. doi: 10.1103/PhysRevLett.91.163001. Epub 2003 Oct 15.

Abstract

Angular distributions of C 1s photoelectrons from fixed-in-space CO molecules have been measured with vibrational resolution. A strong dependence of the angular distributions on the vibrational states of the residual molecular ion has been found for the first time in the region of the shape resonance. Calculations in the relaxed core Hartree-Fock approximation have reproduced the angular distributions fairly well in the general shapes of the angular distributions due to the correct description of nuclear motion as an average of the internuclear-distance-dependent dipole amplitudes.