Slightly weathered Exxon Valdez oil persists in Gulf of Alaska beach sediments after 16 years

Environ Sci Technol. 2007 Feb 15;41(4):1245-50. doi: 10.1021/es0620033.

Abstract

Oil stranded by the 1989 Exxon Valdez spill has persisted in subsurface sediments of exposed shores for 16 years. With annualized loss rates declining from approximately 68% yr(-1) prior to 1992 to approximately 4% yr(-1) after 2001, weathering processes are retarded in both sediments and residual emulsified oil ("oil mousse"), and retention of toxic polycyclic aromatic hydrocarbons is prolonged. The n-alkanes, typically very readily oxidized by microbes, instead remain abundant in many stranded emulsified oil samplesfrom the Gulf of Alaska. They are less abundant in Prince William Sound samples, where stranded oil was less viscous. Our results indicate that, at some locations, remaining subsurface oil may persist for decades with little change.

Publication types

  • Historical Article
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Accidents
  • Alaska
  • Alkanes / analysis*
  • Alkanes / history
  • Environmental Monitoring
  • Environmental Pollutants / analysis*
  • Environmental Pollutants / history
  • Geologic Sediments / analysis
  • History, 20th Century
  • History, 21st Century
  • Petroleum*
  • Polycyclic Aromatic Hydrocarbons / analysis*
  • Polycyclic Aromatic Hydrocarbons / history
  • Ships

Substances

  • Alkanes
  • Environmental Pollutants
  • Petroleum
  • Polycyclic Aromatic Hydrocarbons