An STM study on nonionic fluorosurfactant zonyl FSN self-assembly on Au(111): large domains, few defects, and good stability

Yongan Tang; Jiawei Yan; Xiaoshun Zhou; Yongchun Fu; Bingwei Mao

doi:10.1021/la802682n

An STM study on nonionic fluorosurfactant zonyl FSN self-assembly on Au(111): large domains, few defects, and good stability

Langmuir. 2008 Dec 2;24(23):13245-9. doi: 10.1021/la802682n.

Authors

Yongan Tang¹, Jiawei Yan, Xiaoshun Zhou, Yongchun Fu, Bingwei Mao

Affiliation

¹ State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, Fujian 361005, PR China.

PMID: 18980356
DOI: 10.1021/la802682n

Abstract

Nonionic Fluorosurfactant Zonyl FSN self-assembly on Au(111) is investigated with scanning tunneling microscopy under ambient conditions. STM reveals that the FSN forms SAMs on Au(l11) with very large domain size and almost no defects. A (mean square root of 3 x mean square root of 3)R3 degree arrangement of the FSN SAM on Au(111) is observed. The SAMs show excellent chemical stability and last for at least a month in atmospheric conditions. The structure and stability of the FSN SAMs are compared with those of alkanethiols SAMs. It is expected that FSN may serve as a new kind of molecule to form SAMs for surface modification, which would benefit wider applications for various purposes.