Arylsilane oxidation--new routes to hydroxylated aromatics

Sonia Bracegirdle; Edward A Anderson

doi:10.1039/b924135c

Arylsilane oxidation--new routes to hydroxylated aromatics

Chem Commun (Camb). 2010 May 28;46(20):3454-6. doi: 10.1039/b924135c. Epub 2010 Jan 13.

Authors

Sonia Bracegirdle¹, Edward A Anderson

Affiliation

¹ Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, UKOX1 3TA.

PMID: 20582346
DOI: 10.1039/b924135c

Abstract

An efficient route to hydroxylated aromatics has been developed, via the oxidation of aryl organosilanes under functional group-tolerant and relatively mild conditions, using sub-stoichiometric amounts of fluoride promoters.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Hydrocarbons, Aromatic / chemical synthesis*
Hydrocarbons, Aromatic / chemistry
Molecular Structure
Oxidation-Reduction
Silanes / chemistry*
Stereoisomerism

Substances

Hydrocarbons, Aromatic
Silanes