UV dosage levels in summer: increased risk of ozone loss from convectively injected water vapor

Science. 2012 Aug 17;337(6096):835-9. doi: 10.1126/science.1222978. Epub 2012 Jul 26.

Abstract

The observed presence of water vapor convectively injected deep into the stratosphere over the United States can fundamentally change the catalytic chlorine/bromine free-radical chemistry of the lower stratosphere by shifting total available inorganic chlorine into the catalytically active free-radical form, ClO. This chemical shift markedly affects total ozone loss rates and makes the catalytic system extraordinarily sensitive to convective injection into the mid-latitude lower stratosphere in summer. Were the intensity and frequency of convective injection to increase as a result of climate forcing by the continued addition of CO(2) and CH(4) to the atmosphere, increased risk of ozone loss and associated increases in ultraviolet dosage would follow.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Atmosphere / chemistry*
  • Carbon Dioxide / chemistry
  • Catalysis
  • Chlorine Compounds / chemistry
  • Convection*
  • Methane / chemistry
  • Ozone / chemistry*
  • Radiation Dosage
  • Seasons*
  • Steam*
  • Ultraviolet Rays*

Substances

  • Chlorine Compounds
  • Steam
  • chlorosyl
  • Carbon Dioxide
  • Ozone
  • Methane