Abstract
One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
MeSH terms
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Aldehydes / chemistry
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Cyclization
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Electrolysis
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Indans / chemical synthesis*
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Indans / chemistry*
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Iodides / chemistry*
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Ketones / chemistry
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Molecular Structure
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Samarium / chemistry*
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Stereoisomerism
Substances
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Aldehydes
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Indans
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Iodides
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Ketones
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Samarium
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samarium diiodide