Au40(SR)24 cluster as a chiral dimer of 8-electron superatoms: structure and optical properties

J Am Chem Soc. 2012 Dec 5;134(48):19560-3. doi: 10.1021/ja309619n. Epub 2012 Nov 27.

Abstract

We predict and analyze density-functional theory (DFT)-based structures for the recently isolated Au(40)(SR)(24) cluster. Combining structural information extracted from ligand-exchange reactions, circular dichroism and transmission electron microscopy leads us to propose two families of low-energy structures that have a chiral Au-S framework on the surface. These families have a common geometrical motif where a nonchiral Au(26) bi-icosahedral cluster core is protected by 6 RS-Au-SR and 4 RS-Au-SR-Au-SR oligomeric units, analogously to the "Divide and Protect" motif of known clusters Au(25)(SR)(18)(-/0), Au(38)(SR)(24) and Au(102)(SR)(44). The strongly prolate shape of the proposed Au(26) core is supported by transmission electron microscopy. Density-of-state-analysis shows that the electronic structure of Au(40)(SR)(24) can be interpreted in terms of a dimer of two 8-electron superatoms, where the 8 shell electrons are localized at the two icosahedral halves of the metal core. The calculated optical and chiroptical characteristics of the optimal chiral structure are in a fair agreement with the reported data for Au(40)(SR)(24).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Circular Dichroism
  • Dimerization
  • Electrons*
  • Models, Molecular
  • Organogold Compounds / chemistry*
  • Quantum Theory*
  • Stereoisomerism

Substances

  • Organogold Compounds