cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)

Masatoshi Matsuura; Takashi Fujihara; Akira Nagasawa

doi:10.1107/S1600536813006703

cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 16;69(Pt 4):m209. doi: 10.1107/S1600536813006703. Print 2013 Apr 1.

Authors

Masatoshi Matsuura¹, Takashi Fujihara, Akira Nagasawa

Affiliation

¹ Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-Okubo 255, Sakura-ku, Saitama 338-8570, Japan.

Abstract

The mononuclear title complex, [VCl2O(C3H8S)2], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal-bipyramidal coordination environment defined by two Cl(-) and the S atoms of two (CH3CH2)(CH3)S ligands. In the crystal, pairs of mol-ecules form centrosymmetric dimers via C-H⋯O hydrogen bonds between the methyl C-H group and the oxidovanadium O atom of a neighbouring mol-ecule.