Superhydrophobic and superaerophilic hierarchical Pt@MIL-101/PVDF composite for hydrogen water isotope exchange reactions

Xiaolong Fu; Jingwei Hou; Chao Chen; Jiamao Li; Lei Yue; Xiaojun Chen; Linjie Zhao; Guangming Ran; Xiulong Xia; Yu Gong; Wenjie Ding; Chengjian Xiao; Heyi Wang

doi:10.1016/j.jhazmat.2019.120904

Superhydrophobic and superaerophilic hierarchical Pt@MIL-101/PVDF composite for hydrogen water isotope exchange reactions

J Hazard Mater. 2019 Dec 15:380:120904. doi: 10.1016/j.jhazmat.2019.120904. Epub 2019 Jul 16.

Authors

Xiaolong Fu¹, Jingwei Hou², Chao Chen³, Jiamao Li⁴, Lei Yue⁵, Xiaojun Chen⁶, Linjie Zhao⁷, Guangming Ran⁸, Xiulong Xia⁹, Yu Gong¹⁰, Wenjie Ding¹¹, Chengjian Xiao¹², Heyi Wang¹³

Affiliations

¹ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: fxl@iccas.ac.cn.
² Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: houzi4660@163.com.
³ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: chaochen@caep.cn.
⁴ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: ljmljm2011@126.com.
⁵ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: Yuelei@caep.cn.
⁶ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: xiaojunchen@caep.cn.
⁷ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: zhaolinjie@caep.cn.
⁸ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: guangmingran@caep.cn.
⁹ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: xiaxiulong@caep.cn.
¹⁰ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: gongyu2012@caep.cn.
¹¹ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: dwjcaep@163.com.
¹² Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: xiaocj@caep.cn.
¹³ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, P.O. Box 919-226, Mianyang, Sichuan, 621900, China. Electronic address: hywang@caep.cn.

PMID: 31336270
DOI: 10.1016/j.jhazmat.2019.120904

Abstract

A hierarchical porous composite of Pt@MIL-101/ployvinylidene fluoride (Pt@MIL-101/PVDF) was successfully prepared through a solution-processed method. This composite possesses advanced superhydrophobic and superaerophilic performance which makes it a promising catalyst facilitating liquid phase catalytic exchange techniques (LPCE) in hydrogen-water isotope exchange process. Its superhydrophobic property results in the repellence of water drops from flooding the catalytic surface with a relatively large contact angle in the exchange reaction, and its superaerophilic surface broke hydrogen bubbles into thin film so as to reach higher catalytic reactive efficiency. High reactivity and long-term stability in the reaction process can also be achieved by the configuration of mesoporous cages of MIL-101 confining Pt nanoparticles and preventing them from sintering.

Keywords: Hydrogen isotopes; Hydrogen-water catalytic exchange; Pt@MIL-101/PVDF composite; Superaerophilic; Superhydrophobic.

Publication types

Research Support, Non-U.S. Gov't