1 School of Materials Science and Engineering, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin, 150040, P. R. China. panghj116@163.com mahy017@163.com.
Four new rationally designed polyoxometalate (POM)-based hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 μmol g-1 h-1, which outperform all known POM-based metal-organic photocatalysts.