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A unified view of ligand-protected gold clusters as superatom complexes.
Walter M, Akola J, Lopez-Acevedo O, Jadzinsky PD, Calero G, Ackerson CJ, Whetten RL, Grönbeck H, Häkkinen H. Walter M, et al. Among authors: whetten rl. Proc Natl Acad Sci U S A. 2008 Jul 8;105(27):9157-62. doi: 10.1073/pnas.0801001105. Epub 2008 Jul 1. Proc Natl Acad Sci U S A. 2008. PMID: 18599443 Free PMC article.
Atomically precise Au144(SR)60 nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effects.
Dainese T, Agrachev M, Antonello S, Badocco D, Black DM, Fortunelli A, Gascón JA, Stener M, Venzo A, Whetten RL, Maran F. Dainese T, et al. Among authors: whetten rl. Chem Sci. 2018 Nov 7;9(47):8796-8805. doi: 10.1039/c8sc04092c. eCollection 2018 Dec 21. Chem Sci. 2018. PMID: 30647884 Free PMC article.
On the structure of thiolate-protected Au25.
Akola J, Walter M, Whetten RL, Häkkinen H, Grönbeck H. Akola J, et al. Among authors: whetten rl. J Am Chem Soc. 2008 Mar 26;130(12):3756-7. doi: 10.1021/ja800594p. Epub 2008 Mar 6. J Am Chem Soc. 2008. PMID: 18321117
MicroED Structure of Au146(p-MBA)57 at Subatomic Resolution Reveals a Twinned FCC Cluster.
Vergara S, Lukes DA, Martynowycz MW, Santiago U, Plascencia-Villa G, Weiss SC, de la Cruz MJ, Black DM, Alvarez MM, López-Lozano X, Barnes CO, Lin G, Weissker HC, Whetten RL, Gonen T, Yacaman MJ, Calero G. Vergara S, et al. Among authors: whetten rl. J Phys Chem Lett. 2017 Nov 16;8(22):5523-5530. doi: 10.1021/acs.jpclett.7b02621. Epub 2017 Oct 31. J Phys Chem Lett. 2017. PMID: 29072840 Free PMC article.
87 results