Ginsbach JW - Search Results

1

Experimental Evidence and Mechanistic Description of the Phenolic H-Transfer to the Cu₂O₂ Active Site of oxy-Tyrosinase.

Kipouros I, Stańczak A, Dunietz EM, Ginsbach JW, Srnec M, Rulíšek L, Solomon EI. Kipouros I, et al. Among authors: ginsbach jw. J Am Chem Soc. 2023 Oct 25;145(42):22866-22870. doi: 10.1021/jacs.3c07450. Epub 2023 Oct 16. J Am Chem Soc. 2023. PMID: 37844210 Free PMC article.

2

A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity.

Kim S, Lee JY, Cowley RE, Ginsbach JW, Siegler MA, Solomon EI, Karlin KD. Kim S, et al. Among authors: ginsbach jw. J Am Chem Soc. 2015 Mar 4;137(8):2796-9. doi: 10.1021/ja511504n. Epub 2015 Feb 20. J Am Chem Soc. 2015. PMID: 25697226 Free PMC article.

3

Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry.

Kim S, Ginsbach JW, Lee JY, Peterson RL, Liu JJ, Siegler MA, Sarjeant AA, Solomon EI, Karlin KD. Kim S, et al. Among authors: ginsbach jw. J Am Chem Soc. 2015 Mar 4;137(8):2867-74. doi: 10.1021/ja508371q. Epub 2015 Feb 23. J Am Chem Soc. 2015. PMID: 25706825 Free PMC article.

4

Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy.

Cao R, Saracini C, Ginsbach JW, Kieber-Emmons MT, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Cao R, et al. Among authors: ginsbach jw. J Am Chem Soc. 2016 Jun 8;138(22):7055-66. doi: 10.1021/jacs.6b02404. Epub 2016 May 26. J Am Chem Soc. 2016. PMID: 27228314 Free PMC article.

5

Elucidation of the tyrosinase/O₂/monophenol ternary intermediate that dictates the monooxygenation mechanism in melanin biosynthesis.

Kipouros I, Stańczak A, Ginsbach JW, Andrikopoulos PC, Rulíšek L, Solomon EI. Kipouros I, et al. Among authors: ginsbach jw. Proc Natl Acad Sci U S A. 2022 Aug 16;119(33):e2205619119. doi: 10.1073/pnas.2205619119. Epub 2022 Aug 8. Proc Natl Acad Sci U S A. 2022. PMID: 35939688 Free PMC article.

6

Copper active sites in biology.

Solomon EI, Heppner DE, Johnston EM, Ginsbach JW, Cirera J, Qayyum M, Kieber-Emmons MT, Kjaergaard CH, Hadt RG, Tian L. Solomon EI, et al. Among authors: ginsbach jw. Chem Rev. 2014 Apr 9;114(7):3659-853. doi: 10.1021/cr400327t. Epub 2014 Mar 3. Chem Rev. 2014. PMID: 24588098 Free PMC article. Review. No abstract available.

7

Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium.

Kim S, Ginsbach JW, Billah AI, Siegler MA, Moore CD, Solomon EI, Karlin KD. Kim S, et al. Among authors: ginsbach jw. J Am Chem Soc. 2014 Jun 4;136(22):8063-71. doi: 10.1021/ja502974c. Epub 2014 May 22. J Am Chem Soc. 2014. PMID: 24854766 Free PMC article.

8

Structure/function correlations among coupled binuclear copper proteins through spectroscopic and reactivity studies of NspF.

Ginsbach JW, Kieber-Emmons MT, Nomoto R, Noguchi A, Ohnishi Y, Solomon EI. Ginsbach JW, et al. Proc Natl Acad Sci U S A. 2012 Jul 3;109(27):10793-7. doi: 10.1073/pnas.1208718109. Epub 2012 Jun 18. Proc Natl Acad Sci U S A. 2012. PMID: 22711806 Free PMC article.

9

Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes.

Ginsbach JW, Peterson RL, Cowley RE, Karlin KD, Solomon EI. Ginsbach JW, et al. Inorg Chem. 2013 Nov 18;52(22):12872-4. doi: 10.1021/ic402357u. Epub 2013 Oct 28. Inorg Chem. 2013. PMID: 24164429 Free PMC article.

10

Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.

Peterson RL, Ginsbach JW, Cowley RE, Qayyum MF, Himes RA, Siegler MA, Moore CD, Hedman B, Hodgson KO, Fukuzumi S, Solomon EI, Karlin KD. Peterson RL, et al. Among authors: ginsbach jw. J Am Chem Soc. 2013 Nov 6;135(44):16454-67. doi: 10.1021/ja4065377. J Am Chem Soc. 2013. PMID: 24164682 Free PMC article.

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