A New Preparative Method for Allylic Indium(III) Reagents by Reductive Transmetalation of pi-Allylpalladium(II) with Indium(I) Salts

S Araki; T Kamei; T Hirashita; H Yamamura; M Kawai

doi:10.1021/ol005610i

A New Preparative Method for Allylic Indium(III) Reagents by Reductive Transmetalation of pi-Allylpalladium(II) with Indium(I) Salts

Org Lett. 2000 Mar 23;2(6):847-849. doi: 10.1021/ol005610i.

Authors

S Araki¹, T Kamei, T Hirashita, H Yamamura, M Kawai

Affiliation

¹ Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.

PMID: 10814439
DOI: 10.1021/ol005610i

Abstract

A reductive transmetalation of the pi-allylpalladium(II) complexes, generated in situ from a catalytic amount of a palladium(0) complex and a variety of allylic substrates, with indium(I) salts proceeded smoothly in various solvents, providing a new route for allylindium(III) reagents.