(Benzoxazole-2-thiolato-S)(benzoxazole-2-thione-S)bis(triphenylphosph ine)copper(I)

T Nakahodo; E Horn; E R Tiekink

doi:10.1107/s0108270100011483

(Benzoxazole-2-thiolato-S)(benzoxazole-2-thione-S)bis(triphenylphosph ine)copper(I)

Acta Crystallogr C. 2000 Nov:56 Pt 11:1316-8. doi: 10.1107/s0108270100011483.

Authors

T Nakahodo¹, E Horn, E R Tiekink

Affiliation

¹ Department of Chemistry, Rikkyo University, Nishi-Ikebukuro, Tokyo 171-8501, Japan.

PMID: 11077282
DOI: 10.1107/s0108270100011483

Abstract

The Cu atom in [Cu(C(7)H(4)NOS)(C(7)H(5)NOS)(C(18)H(15)P)(2)] is tetrahedrally coordinated by a P(2)S(2) donor set. One S atom is derived from neutral benzoxazole-2-thione and the other from the deprotonated form of the ligand. The two sulfur ligands are connected via an N-H.N interaction, leading to the formation of an eight-membered ring.