(Z)-7-Chloro-3-[(3-chlorophenyl)-methylidene]-4-p-tosyl-3,4-dihydro-2H-1,4-benzoxazine

Acta Crystallogr C. 2001 Jun;57(Pt 6):740-1. doi: 10.1107/s0108270101004036. Epub 2001 Jun 12.

Abstract

In the title compound, C22H17Cl2NO3S, the molecule is a substituted 3,4-dihydro-2H-1,4-benzoxazine compound which has three phenyl rings which are essentially planar. The 3,4-dihydro-2H-oxazine part of the molecule is fused to the benzo ring and has a half-boat conformation; the dihedral angle between the planar part of the oxazine ring and the benzo ring is 10.2 (2) degrees. The (3-chlorophenyl)methylidene substituent has a Z configuration in relation to the ring N atom of the oxazine moiety. Interestingly, the p-toluenesulfonyl (p-tosyl) substituent on the ring N atom protrudes away from the 3-chlorophenyl substituent thus avoiding any steric interaction.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Molecular Structure
  • Oxazines / chemistry*
  • Tosyl Compounds / chemistry*

Substances

  • 7-Chloro-3-((3-chlorophenyl)-methylidene)-4-p-tosyl-3,4-dihydro-2H-1,4-benzoxazine
  • Oxazines
  • Tosyl Compounds