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. 2001 Sep 6;3(18):2843-5.
doi: 10.1021/ol016286+.

Synthesis of (+)-Galiellalactone. Absolute Configuration of Galiellalactone

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Synthesis of (+)-Galiellalactone. Absolute Configuration of Galiellalactone

M Johansson et al. Org Lett. .

Abstract

[reaction: see text]. (+)-Galiellalactone was synthesized starting from (R)-(+)-pulegone. Natural and synthetic galiellalactone have opposite optical rotations, demonstrating that the structure of the natural product is 1a.

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