The photodissociation dynamics of [Re(H)(CO)(3)(H-dab)] (H-dab=1,4-diaza-1,3-butadiene) were studied by means of wavepacket propagations on CASSCF/MR-CCI potentials calculated for the electronic ground state and low-lying excited states as a function of two coordinates, q(a) and q(b), that correspond to the Re-H bond homolysis and to the axial CO loss, respectively. The theoretical absorption spectrum is characterized by two bands, one intense peak centered at lambda=500 nm (21,000 cm(-1)) and one broad band centered at 310 nm (32,500 cm(-1)). The visible band was assigned to the low-lying metal-to-ligand charge-transfer (MLCT) states with a main contribution of the a(1)A'-->c(1)A' transition corresponding to the 3d(xz)-->pi*(dab) excitation. The second band calculated in the UV energy domain was assigned to the d(1)A' (sigma(Mn-H)-->pi*(dab)) state corresponding to a sigma-bond-to-ligand charge-transfer (SBLCT) state. The photodissociation dynamics of the low-lying (1)MLCT and (3)SBLCT states following irradiation in the visible energy domain was simulated by wavepacket propagation on the two-dimensional diabatic potentials V(q(a), q(b)) coupled by the spin-orbit. In contrast to what was found for the manganese analogue, the (1)MLCT state is nonreactive and a rather slow (beyond the ps time scale), nontotal and indirect homolysis of the Re-H bond occurs through (1)MLCT-->(3)SBLCT intersystem crossing.