Abstract
A variety of 3-substituted furans, including the natural products perillene and dendrolasin, are obtained in good yield via reductive annulation of 1,1,1-trichloroethyl propargyl ethers using catalytic Cr(II) regenerated by Mn/TMSCl. [reaction: see text]
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Acyclic Monoterpenes
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Alkylation
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Chlorides
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Chromium Compounds
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Furans / chemical synthesis*
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Indicators and Reagents
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Monoterpenes*
Substances
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Acyclic Monoterpenes
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Chlorides
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Chromium Compounds
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Furans
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Indicators and Reagents
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Monoterpenes
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dendrolasin
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perillene
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chromous chloride