Aqueous enantioselective hydrogenation of methyl 2-acetamidoacrylate with Rh-MeDuPHOS occluded in PDMS

Adi Wolfson; Sofie Janssens; Ivo Vankelecom; Shimona Geresh; Moshe Gottlieb; Moti Herskowitz

doi:10.1039/b109234k

Aqueous enantioselective hydrogenation of methyl 2-acetamidoacrylate with Rh-MeDuPHOS occluded in PDMS

Chem Commun (Camb). 2002 Feb 21:(4):388-9. doi: 10.1039/b109234k.

Authors

Adi Wolfson¹, Sofie Janssens, Ivo Vankelecom, Shimona Geresh, Moshe Gottlieb, Moti Herskowitz

Affiliation

¹ Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

PMID: 12120088
DOI: 10.1039/b109234k

Abstract

A new chiral heterogeneous catalytic system obtained by occlusion of the Rh-MeDuPHOS complex in a polydimethylsiloxane film was tested in the asymmetric hydrogenation of methyl 2-acetamidoacrylate in aqueous medium.