Post-translational modification of bone morphogenetic protein-1 is required for secretion and stability of the protein

J Biol Chem. 2002 Nov 8;277(45):43327-34. doi: 10.1074/jbc.M207342200. Epub 2002 Sep 5.

Abstract

Bone morphogenetic protein (BMP)-1 is a glycosylated metalloproteinase that is fundamental to the synthesis of a normal extracellular matrix because it cleaves type I procollagen, as well as other precursor proteins. Sequence analysis suggests that BMP-1 has six potential N-linked glycosylation sites (i.e. NXS/T) namely: Asn(91) (prodomain), Asn(142) (metalloproteinase domain), Asn(332) and Asn(363) (CUB1 domain), Asn(599) (CUB3 domain), and Asn(726) in the C-terminal-specific domain. In this study we showed that all these sites are N-glycosylated with complex-type oligosaccharides containing sialic acid, except Asn(726) presumably because proline occurs immediately C-terminal of threonine in the consensus sequence. Recombinant BMP-1 molecules lacking all glycosylation sites or the three CUB-specific sites were not secreted. BMP-1 lacking CUB glycosylation was translocated to the proteasome for degradation. BMP-1 molecules lacking individual glycosylation sites were efficiently secreted and exhibited full procollagen C-proteinase activity, but N332Q and N599Q exhibited a slower rate of cleavage. BMP-1 molecules lacking any one of the CUB-specific glycosylation sites were sensitive to thermal denaturation. The study showed that the glycosylation sites in the CUB domains of BMP-1 are important for secretion and stability of the molecule.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Substitution
  • Base Sequence
  • Bone Morphogenetic Protein 1
  • Bone Morphogenetic Proteins / chemistry
  • Bone Morphogenetic Proteins / metabolism*
  • Cell Line
  • DNA Primers
  • Enzyme Stability
  • Fibrosarcoma
  • Glycosylation
  • Humans
  • Kidney
  • Kinetics
  • Metalloendopeptidases / chemistry
  • Metalloendopeptidases / metabolism*
  • Microscopy, Fluorescence
  • Mutagenesis, Site-Directed
  • Polymerase Chain Reaction
  • Protein Processing, Post-Translational*
  • Substrate Specificity
  • Transfection
  • Tumor Cells, Cultured

Substances

  • Bone Morphogenetic Proteins
  • DNA Primers
  • Metalloendopeptidases
  • BMP1 protein, human
  • Bone Morphogenetic Protein 1