Intrachain energy transfer in silylene-spaced alternating donor-acceptor divinylarene copolymers

Yen-Jun Cheng; Tsyr-Yuan Hwu; Jui-Hung Hsu; Tien-Yau Luh

doi:10.1039/b206308e

Intrachain energy transfer in silylene-spaced alternating donor-acceptor divinylarene copolymers

Chem Commun (Camb). 2002 Sep 7:(17):1978-9. doi: 10.1039/b206308e.

Authors

Yen-Jun Cheng¹, Tsyr-Yuan Hwu, Jui-Hung Hsu, Tien-Yau Luh

Affiliation

¹ Department of Chemistry, National Taiwan University, Taipei, Taiwan 106. Institute of Chemistry, Academia Sinica, Taipei, Taiwan 115.

PMID: 12271703
DOI: 10.1039/b206308e

Abstract

Silylene-spaced donor-acceptor divinylarene copolymers are synthesized by hydrosilylation of bisalkynes 7 with bisvinylsilanes 3; efficient intrachain energy transfer between donor-acceptor chromophores is observed.