An assembled complex of palladium and non-cross-linked amphiphilic polymer: a highly active and recyclable catalyst for the Suzuki-Miyaura reaction

Yoichi M A Yamada; Koji Takeda; Hideyo Takahashi; Shiro Ikegami

doi:10.1021/ol0264612

An assembled complex of palladium and non-cross-linked amphiphilic polymer: a highly active and recyclable catalyst for the Suzuki-Miyaura reaction

Org Lett. 2002 Oct 3;4(20):3371-4. doi: 10.1021/ol0264612.

Authors

Yoichi M A Yamada¹, Koji Takeda, Hideyo Takahashi, Shiro Ikegami

Affiliation

¹ Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa 199-0195, Japan.

PMID: 12323021
DOI: 10.1021/ol0264612

Abstract

An insoluble and assembled catalyst of palladium and a non-cross-linked amphiphilic polymer were developed. In the presence of 50-500 ppm mol equiv of catalyst, the Suzuki-Miyaura reaction proceeded efficiently under organic solvent-free conditions. The catalyst was reused 10 times without any decrease in activity and was recycled without any special treatment.[structure: see text]