Synthesis and crystal structure of IM-6, a new open framework cobalt-gallium phosphate with ten- and twelve-membered pore openings

Ludovic Josien; Angélique Simon-Masseron; Volker Gramlich; Joël Patarin; Loïc Rouleau

doi:10.1002/chem.200390095

Synthesis and crystal structure of IM-6, a new open framework cobalt-gallium phosphate with ten- and twelve-membered pore openings

Chemistry. 2003 Feb 17;9(4):856-61. doi: 10.1002/chem.200390095.

Authors

Ludovic Josien¹, Angélique Simon-Masseron, Volker Gramlich, Joël Patarin, Loïc Rouleau

Affiliation

¹ Laboratoire de Matériaux Minéraux, ENSCMu Université de Haute Alsace, CNRS UMR 7016, 3 rue Alfred Werner, 68093 Mulhouse Cedex, France.

PMID: 12584700
DOI: 10.1002/chem.200390095

Abstract

A new three-dimensional microporous cobalt-gallium phosphate, named IM-6, has been synthesized under solvothermal conditions with an N-substituted piperazine as organic template. The structure was solved by single-crystal X-ray diffraction (triclinic, P(-)1, a=9.848(20), b=12.470(32), c=12.603(28)A, alpha=63.47(16) degrees, beta=74.56(16) degrees, gamma=76.03(17) degrees). IM-6 exhibits a new framework topology. The inorganic framework is built up of MO(4) (M=Co, Ga) and PO(4) tetrahedra. It displays a two-dimensional interconnected channel system running along the [0(-)11] and [100] directions and delimited by ten- and twelve-membered ring openings, respectively.