Abstract
The title compounds were prepared from a common precursor, a bis-THP-protected dihydroxyphenylacetic acid methyl ester. Key steps are the introduction of the alpha-hydroxyl group by Davis oxaziridine reagent and formation of the aldehydes by DIBALH ester reduction.
MeSH terms
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3,4-Dihydroxyphenylacetic Acid / analogs & derivatives*
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3,4-Dihydroxyphenylacetic Acid / chemical synthesis*
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3,4-Dihydroxyphenylacetic Acid / chemistry
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Aldehydes / chemical synthesis*
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Aldehydes / chemistry
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Catechols
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Hydrolysis
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Hydroxyl Radical / chemistry
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Indicators and Reagents
Substances
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Aldehydes
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Catechols
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Indicators and Reagents
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3,4-Dihydroxyphenylacetic Acid
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3,4-dihydroxyphenylglycolaldehyde
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Hydroxyl Radical
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3,4-dihydroxyphenylacetaldehyde