Quasi-1D cations 1 infinity [Ni8Bi8S]n + of variable charge: infinite columns 1 infinity [Ni8Bi8S]2+ in the novel compound Ni8Bi8SI2

A I Baranov; L Kloo; A V Olenev; B A Popovkin; A I Romanenko

doi:10.1021/ic0340332

Quasi-1D cations 1 infinity [Ni8Bi8S]n + of variable charge: infinite columns 1 infinity [Ni8Bi8S]2+ in the novel compound Ni8Bi8SI2

Inorg Chem. 2003 Jun 30;42(13):3988-93. doi: 10.1021/ic0340332.

Authors

A I Baranov¹, L Kloo, A V Olenev, B A Popovkin, A I Romanenko

Affiliation

¹ Department of Materials Science, Moscow State University, Vorob'evy Gory, Moscow, 119992, Russia.

PMID: 12817954
DOI: 10.1021/ic0340332

Abstract

The new compound Ni(8)Bi(8)SI(2) has been synthesized and its crystal structure determined by X-ray crystallography. The structure contains one-dimensional (1D) cations (1)( infinity )[Ni(8)Bi(8)S](2+) separated by iodine anions. The geometry of the columns is similar to that of the recently reported (1)( infinity )[Ni(8)Bi(8)S](+), and the main difference between them is only their formal charge. Electronic structure calculations and physical properties measurements were performed to analyze the influence of the number of valence electrons on the bonding and properties of compounds containing these 1D cations. It was shown that the removal of one electron (i.e., (1)( infinity )[Ni(8)Bi(8)S](+) --> (1)( infinity )[Ni(8)Bi(8)S](2+)) mainly affects the Ni-S bonding within the cation and essentially has no influence on the intermetallic Ni-Bi bonding. It was found that Ni(8)Bi(8)SI(2) containing double-charged columns has conductivity properties more similar to a pure 1D metal than the congener Ni(8)Bi(8)SI containing mono-charged columns.