Ferromagnetic ordering and metamagnetism in malonate bridged 3D diamond-like and honeycomb-like networks: [Cu(mal)(DMF)]n and [[Cu(mal)(0.5pyz)].H2O]n (mal = Malonate Dianion, DMF = N,N-dimethylformamide, pyz = Pyrazine)

Tian-Fu Liu; Hao-Ling Sun; Song Gao; Shi-Wei Zhang; Tai-Chu Lau

doi:10.1021/ic034346x

Ferromagnetic ordering and metamagnetism in malonate bridged 3D diamond-like and honeycomb-like networks: [Cu(mal)(DMF)]n and [[Cu(mal)(0.5pyz)].H2O]n (mal = Malonate Dianion, DMF = N,N-dimethylformamide, pyz = Pyrazine)

Inorg Chem. 2003 Aug 11;42(16):4792-4. doi: 10.1021/ic034346x.

Authors

Tian-Fu Liu¹, Hao-Ling Sun, Song Gao, Shi-Wei Zhang, Tai-Chu Lau

Affiliation

¹ College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, P.R. China.

PMID: 12895096
DOI: 10.1021/ic034346x

Abstract

Two three-dimensional (3D) malonate bridged networks, [Cu(mal)(DMF)](n) (1) and [[Cu(mal)(0.5pyz)].H(2)O](n) (2), have been synthesized in H(2)O-DMF solution. Compound 1 exhibits ferromagnetic ordering below 2.6 K (T(c)), and 2 displays a metamagnetic behavior below 3.2 K (T(N)).