1 Department of Chemistry, Faculty of Engineering Sciences, Osaka University, and CREST, Japan Science and Technology Corporation (JST), Toyonaka, Osaka 560-8531, Japan.
[reaction: see text] Synthesis of aromatic ring substituted (E)-1,1'-biindenylidene derivatives was achieved by a domino-Heck type double cyclization of (Z,Z)-1,6-diaryl-1,5-hexadien-3-ynes.