An abrupt spin transition based on short S...S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring

Chem Commun (Camb). 2003 Sep 21:(18):2374-5. doi: 10.1039/b308070f.

Abstract

The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S...S contacts play a key role in an abrupt spin transition.