Abstract
[reaction: see text]. Enolate amination using O-di(p-methoxyphenyl)phosphinylhydroxylamine 2 is reported. Reagent 2 reacts efficiently with stabilized sodium or potassium enolates derived from malonates, phenylacetates, and phenylacetonitriles and is sufficiently soluble for use in solution at -78 degrees C.
Publication types
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Acetonitriles / chemistry
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Amination*
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Anions / chemistry*
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Catalysis
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Hydroxylamines / chemistry
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Malonates / chemistry
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Molecular Structure
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Organic Chemicals / chemistry*
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Organophosphorus Compounds / chemistry
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Phenylacetates / chemistry
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Phosphinic Acids / chemistry
Substances
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Acetonitriles
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Anions
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Hydroxylamines
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Malonates
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Organic Chemicals
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Organophosphorus Compounds
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Phenylacetates
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Phosphinic Acids
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benzyl cyanide