Abstract
Primary amine hydrochlorides promote a well-controlled ring-opening polymerisation of Z-L-lysine-N-carboxyanhydride in DMF at 40-80 degrees C; the polystyrene-poly(Z-L-lysine) block copolymers synthesised exhibit a very narrow molecular weight distribution, close to a Poisson distribution.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Anhydrides / chemistry*
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Magnetic Resonance Spectroscopy
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Molecular Structure
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Polylysine / chemistry*
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Polymers / chemical synthesis*
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Polymers / chemistry*
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Polystyrenes / chemistry*
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Temperature
Substances
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Anhydrides
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Polymers
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Polystyrenes
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Polylysine