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, (4), 466-7

A Novel Synthesis of Chiral Rotaxanes via Covalent Bond Formation

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A Novel Synthesis of Chiral Rotaxanes via Covalent Bond Formation

Naohiro Kameta et al. Chem Commun (Camb).

Abstract

Chiral rotaxanes composed of the asymmetric crownophane incorporating two hydroxy groups as a rotor moiety and the asymmetric axis were effectively synthesized via covalent bond formation, i.e. tandem Claisen rearrangement, esterification, and aminolysis.

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