Heck vinylation of aryl iodides by a silica sol-gel entrapped Pd(II) catalyst and its combination with a photocyclization process

Khalil Hamza; Raed Abu-Reziq; David Avnir; Jochanan Blum

doi:10.1021/ol030140o

Heck vinylation of aryl iodides by a silica sol-gel entrapped Pd(II) catalyst and its combination with a photocyclization process

Org Lett. 2004 Mar 18;6(6):925-7. doi: 10.1021/ol030140o.

Authors

Khalil Hamza¹, Raed Abu-Reziq, David Avnir, Jochanan Blum

Affiliation

¹ Department of Organic Chemistry, The Hebrew University, Jerusalem 91904, Israel.

PMID: 15012066
DOI: 10.1021/ol030140o

Abstract

[reaction: see text] Silica sol-gel encaged PdCl(2)(PPh(3))(2) is a recyclable catalyst for the Heck vinylation of aryl iodides. It is possible to couple the Heck reaction with photocyclization in a one-pot process.