Alkynylxenon(II) fluorides

Harald Schmidt; Harald Scherer; Wieland Tyrra; Josef Hahn; Dieter Naumann

doi:10.1021/ic035394k

Alkynylxenon(II) fluorides

Inorg Chem. 2004 Mar 22;43(6):1837-9. doi: 10.1021/ic035394k.

Authors

Harald Schmidt¹, Harald Scherer, Wieland Tyrra, Josef Hahn, Dieter Naumann

Affiliation

¹ Universität zu Köln, Institut für Anorganische Chemie, Greinstrasse 6, 50939 Köln, Germany.

PMID: 15018501
DOI: 10.1021/ic035394k

Abstract

Alkynylxenon(II) fluorides, RCC(triple bond)XeF, have been prepared from the reactions of the corresponding trimethyl(alkynyl)silanes, Me3(-)SiC(triple bond)CR, and XeF2 in the presence of [NMe4F in common organic solvents at low temperature. The existence of the linear unit C(triple bond)C-Xe-F was proved for PhC(triple bond)CXeF by the 19F-13C NMR correlation method using the HMBC pulse sequence.