Poly[[aquaneodymium(III)]-micro(3)-decane-1,10-dicarboxylato-micro(3)-9-carboxynonanecarboxylato]

Lauren A Borkowski; Christopher L Cahill

doi:10.1107/S0108270104003427

Poly[[aquaneodymium(III)]-micro(3)-decane-1,10-dicarboxylato-micro(3)-9-carboxynonanecarboxylato]

Acta Crystallogr C. 2004 Apr;60(Pt 4):m159-61. doi: 10.1107/S0108270104003427. Epub 2004 Mar 11.

Authors

Lauren A Borkowski¹, Christopher L Cahill

Affiliation

¹ Department of Chemistry, George Washington University, 725 21st Street NW, Washington, DC 20052, USA.

PMID: 15071203
DOI: 10.1107/S0108270104003427

Abstract

The title compound, [Nd(C(10)H(16)O(4))(C(10)H(17)O(4))(H(2)O)](n), has a novel Nd-organic framework constructed from sebacic acid (C(10)H(18)O(4)) linkers, the longest aliphatic ligand used to date in lanthanide metal-organic framework compounds. The structure contains edge-shared chains of NdO(8)(H(2)O) tricapped trigonal prisms that propagate in the [100] direction, with Nd-O distances in the range 2.414 (4)-2.643 (4) A.