Light-driven molecular hinge: a new molecular machine showing a light-intensity-dependent photoresponse that utilizes the trans-cis isomerization of azobenzene

Yasuo Norikane; Nobuyuki Tamaoki

doi:10.1021/ol049082c

Light-driven molecular hinge: a new molecular machine showing a light-intensity-dependent photoresponse that utilizes the trans-cis isomerization of azobenzene

Org Lett. 2004 Jul 22;6(15):2595-8. doi: 10.1021/ol049082c.

Authors

Yasuo Norikane¹, Nobuyuki Tamaoki

Affiliation

¹ National Institute of Advanced Industrial Science and Technology (AIST), Central 5, 1-1-1, Higashi, Tsukuba, Ibaraki, 305-8565, Japan.

PMID: 15255699
DOI: 10.1021/ol049082c

Abstract

[reaction: see text] A new class of molecular machine exhibits a hingelike motion upon photoirradiation. The motion (close and open) can be operated by alternate irradiation with UV and visible light. The trans/trans and cis/cis isomers are thermally stable at 40 degrees C, and the photochemical closure reaction (from trans/trans to cis/cis isomer) is dependent on the intensity of the light used because of the short-lived intermediate (trans/cis isomer).