Inclusion of C60 into an adjustable porphyrin dimer generated by dynamic disulfide chemistry

Chem Commun (Camb). 2005 Mar 14:(10):1276-8. doi: 10.1039/b417951j. Epub 2005 Jan 20.

Abstract

A new, highly flexible porphyrin dimer was isolated in preparative scale from a dynamic disulfide library; this receptor adjusts to fit guests with a wide range of steric requirements and, whilst C60 proved to be an unsuitable template for this library, a new C60-porphyrin complex was isolated and characterised.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Combinatorial Chemistry Techniques / methods
  • Crystallography, X-Ray
  • Dimerization
  • Disulfides / chemistry*
  • Fullerenes / chemistry*
  • Magnetic Resonance Spectroscopy / methods
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Organometallic Compounds / isolation & purification
  • Porphyrins / chemistry*
  • Sensitivity and Specificity
  • Zinc / chemistry*

Substances

  • Disulfides
  • Fullerenes
  • Organometallic Compounds
  • Porphyrins
  • Zinc
  • fullerene C60