Abstract
[reaction: see text] The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Acetals / chemical synthesis
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Acetals / chemistry
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Catalysis
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Cyclization
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Hydrocarbons / chemistry
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Indicators and Reagents
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Ions / chemistry
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Methane / analogs & derivatives*
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Methane / chemistry
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Models, Chemical*
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Molecular Structure
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Oxidation-Reduction
Substances
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Acetals
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Hydrocarbons
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Indicators and Reagents
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Ions
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carbene
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Methane