Anion-assisted trans-cis isomerization of palladium(II) phosphine complexes containing acetanilide functionalities through hydrogen bonding interactions

Chem Commun (Camb). 2005 Mar 28;(12):1572-4. doi: 10.1039/b418202b. Epub 2005 Feb 2.

Abstract

The anion-assisted shift of trans-cis isomerization equilibrium of a palladium(II) complex containing acetanilide functionalities brought about by allosteric hydrogen bonding interactions has been established by UV/Vis, 1H NMR, 31P NMR and ESI-MS studies.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetanilides / chemistry*
  • Anions
  • Hydrogen Bonding
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Palladium / chemistry*
  • Palladium / metabolism
  • Phosphines / chemistry*
  • Phosphines / metabolism
  • Spectrum Analysis
  • Stereoisomerism

Substances

  • Acetanilides
  • Anions
  • Phosphines
  • Palladium
  • phosphine
  • acetanilide