Isethionate as a product from taurine during nitrogen-limited growth of Klebsiella oxytoca TauN1

Arch Microbiol. 2005 Aug;183(5):325-30. doi: 10.1007/s00203-005-0776-7. Epub 2005 May 10.

Abstract

Klebsiella oxytoca TauN1 represents a group of isolates which utilise taurine (2-aminoethanesulfonate) quantitatively as a sole source of combined nitrogen for aerobic growth. During growth, a compound is excreted, which has now been identified as isethionate (2-hydroxyethanesulfonate). An ion-chromatographic separation of isethionate was developed to quantify the putative isethionate, whose identity was confirmed by matrix-assisted, laser-desorption ionisation time-of-flight mass spectrometry. Strain TauN1 utilised taurine (and excreted isethionate) concomitantly with growth. Cell-free extracts contained inducible taurine transaminase, which yielded sulfoacetaldehyde. A soluble, NADP-dependent isethionate dehydrogenase converted sulfoacetaldehyde to isethionate. The enzyme was partially purified and it apparently belonged to the family of short-chain alcohol dehydrogenases.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetaldehyde / analogs & derivatives
  • Acetaldehyde / metabolism
  • Alcohol Oxidoreductases / metabolism
  • Enzyme Induction
  • Isethionic Acid / metabolism*
  • Klebsiella oxytoca / growth & development
  • Klebsiella oxytoca / metabolism*
  • Nitrogen / metabolism
  • Taurine / metabolism*
  • Transaminases / biosynthesis

Substances

  • phosphonoacetaldehyde
  • Taurine
  • Isethionic Acid
  • Alcohol Oxidoreductases
  • isethionate dehydrogenase
  • Transaminases
  • taurine aminotransferase
  • Acetaldehyde
  • Nitrogen