Highly sensitive analysis of the anti-tumor agent 1-[4-(furo[2,3-b]-quinolin-4-ylamino)phenyl]ethanone in rat plasma by high-performance liquid chromatography using electrochemical detection

J Pharm Biomed Anal. 2005 Jul 1;38(3):551-5. doi: 10.1016/j.jpba.2005.01.018. Epub 2005 Feb 24.

Abstract

A sensitive high-performance liquid chromatography method with electrochemical detection was developed for the purpose of determining the concentration of the new anti-tumor agent 1-[4-(furo[2,3-b]-quinolin-4-ylamino)phenyl]ethanone (FQPE) in rats. The plasma samples were spiked with the internal standard diclofenac and extracted using dichloromethane. A C(18) 250 mm x 4mm column was used for the separation of analyte with a mobile phase consisting of 50% acetonitrile and 50% pH 3.0 of sodium 1-pentansulfonate solution at a flow rate of 1.0 mL/min. FQPE was detected by electrochemical detector at 1.0 V and 20 nA. Intra-day and inter-day precision and accuracy were acceptable down to the limit of quantization of 1 ng/mL. The lower limit of detection (LOD) was 0.5 ng/mL. The pharmacokinetic parameters of FQPE in rats after intravenous administration of 2.1 and 4.2 mg/kg were determined. The apparent volume of distribution, half-life of elimination, and clearance showed no significant difference between the two dosages. The area under the plasma concentration time curve increased proportionally with dose. The half-life of FQPE was prolonged about 2.4-fold, compared with amsacrine.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amsacrine / blood
  • Amsacrine / chemistry
  • Amsacrine / pharmacokinetics
  • Animals
  • Antineoplastic Agents / blood*
  • Antineoplastic Agents / chemistry
  • Antineoplastic Agents / pharmacokinetics
  • Area Under Curve
  • Chromatography, High Pressure Liquid / methods*
  • Drug Screening Assays, Antitumor / methods
  • Electrochemistry / methods*
  • Half-Life
  • Molecular Structure
  • Quinolines / blood*
  • Quinolines / chemistry
  • Quinolines / pharmacokinetics
  • Rats
  • Rats, Wistar
  • Reproducibility of Results
  • Technology, Pharmaceutical / methods

Substances

  • 1-(4-(furo(2,3-b)quinolin-4-ylamino)phenyl)ethanone
  • Antineoplastic Agents
  • Quinolines
  • Amsacrine