The studies performed with chiral oxazolines as vehicles for a number of C-C bond-forming reactions are traced back to the early 1970s. The main source of chirality in these studies was derived from chiral, nonracemic amino alcohols which, themselves, were prepared from amino acids. The formation of chiral oxazolines from these materials provided interesting and useful starting materials for these studies. The factors responsible for high optical yields during that era were attributed to rigidity or precomplexation of the reactants, thus providing a more well-defined topography during the reaction course. A number of C-C bond reaction types are described including alkylations, additions, and organometallic reactions. The ee's of many of the products arrived at are well above 90%. This level of ee was virtually unprecedented in the early to mid 1970s. In addition to the synthetic emphasis, several mechanistic questions, arising in other areas, were also undertaken due to the accessibility of the appropriate requisite chiral materials.