Stable Cyclic (Alkyl)(amino)carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference

Angew Chem Int Ed Engl. 2005 Sep 5;44(35):5705-9. doi: 10.1002/anie.200501841.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amines / chemical synthesis*
  • Amines / chemistry
  • Catalysis
  • Crystallography, X-Ray
  • Electrons
  • Hydrocarbons / chemical synthesis
  • Hydrocarbons / chemistry
  • Hydrocarbons, Cyclic / chemical synthesis*
  • Hydrocarbons, Cyclic / chemistry
  • Metals / chemistry*
  • Methane / analogs & derivatives*
  • Methane / chemical synthesis
  • Methane / chemistry
  • Models, Molecular
  • Molecular Structure

Substances

  • Amines
  • Hydrocarbons
  • Hydrocarbons, Cyclic
  • Metals
  • carbene
  • Methane