Crystal structure at high resolution of ferric-pyochelin and its membrane receptor FptA from Pseudomonas aeruginosa

J Mol Biol. 2005 Sep 30;352(4):893-904. doi: 10.1016/j.jmb.2005.08.004.

Abstract

Pyochelin is a siderophore and virulence factor common to Burkholderia cepacia and several Pseudomonas strains. We describe at 2.0 A resolution the crystal structure of the pyochelin outer membrane receptor FptA bound to the iron-pyochelin isolated from Pseudomonas aeruginosa. One pyochelin molecule bound to iron is found in the protein structure, providing the first three-dimensional structure at the atomic level of this siderophore. The pyochelin molecule provides a tetra-dentate coordination of iron, while the remaining bi-dentate coordination is ensured by another molecule not specifically recognized by the protein. The overall structure of the pyochelin receptor is typical of the TonB-dependent transporter superfamily, which uses the proton motive force from the cytoplasmic membrane through the TonB-ExbB-ExbD energy transducing complex to transport ferric ions across the bacterial outer membrane: a transmembrane 22 beta-stranded barrel occluded by a N-terminal domain that contains a mixed four-stranded beta-sheet. The N-terminal TonB box is disordered in two crystal forms, and loop L8 is found to point towards the iron-pyochelin complex, suggesting that the receptor is in a transport-competent conformation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Bacterial Outer Membrane Proteins / chemistry*
  • Bacterial Outer Membrane Proteins / metabolism
  • Binding Sites
  • Crystallography, X-Ray
  • Iron / chemistry*
  • Iron / metabolism
  • Iron Chelating Agents / chemistry*
  • Iron Chelating Agents / metabolism
  • Models, Molecular
  • Molecular Sequence Data
  • Molecular Structure
  • Phenols / chemistry*
  • Phenols / metabolism
  • Protein Binding
  • Protein Structure, Quaternary*
  • Protein Structure, Secondary
  • Pseudomonas aeruginosa / metabolism*
  • Receptors, Cell Surface / chemistry*
  • Receptors, Cell Surface / metabolism
  • Siderophores / chemistry*
  • Siderophores / metabolism
  • Thiazoles / chemistry*
  • Thiazoles / metabolism

Substances

  • Bacterial Outer Membrane Proteins
  • FPTA protein, Pseudomonas
  • Iron Chelating Agents
  • Phenols
  • Receptors, Cell Surface
  • Siderophores
  • Thiazoles
  • pyochelin
  • Iron

Associated data

  • PDB/1XKW