Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111)

Stephan Hermes; Felicitas Schröder; Rolf Chelmowski; Christof Wöll; Roland A Fischer

doi:10.1021/ja053523l

Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111)

J Am Chem Soc. 2005 Oct 12;127(40):13744-5. doi: 10.1021/ja053523l.

Authors

Stephan Hermes¹, Felicitas Schröder, Rolf Chelmowski, Christof Wöll, Roland A Fischer

Affiliation

¹ Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universität Bochum, D-44870 Bochum, Germany.

PMID: 16201767
DOI: 10.1021/ja053523l

Abstract

Metal-Organic open Framework coordination polymers (MOFs) are a fascinating class of materials. We demonstrate the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters inside the cavities of the MOF-5 material.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Gold / chemistry*
Membranes, Artificial*
Models, Molecular
Organometallic Compounds / chemistry*
Particle Size
Surface Properties

Substances

Membranes, Artificial
Organometallic Compounds
Gold