Development of a disposable pyruvate biosensor to determine pungency in onions (Allium cepa L.)

Biosens Bioelectron. 2006 May 15;21(11):2176-9. doi: 10.1016/j.bios.2005.10.024. Epub 2005 Dec 5.

Abstract

A disposable prototype pyruvate biosensor was constructed using pyruvate oxidase immobilised on mediated meldolas blue electrodes to determine pungency in onions (Allium cepa L.). The optimum operating potential was +150 mV (versus Ag/AgCl). A strong correlation between the biosensor response and untreated onion juice of known pyruvate concentration 2-12 micromol/g fresh weight (FW) was demonstrated. The biosensor was able to differentiate between low and high pungency onions. The detection limit using 1 unit of pyruvate oxidase was 1-2 micromol/g FW. Optimum concentrations of co-factors TPP, FAD and MgSO4 comprising the enzyme cocktail were determined as being 0.04, 0.1 and 30 mM, respectively.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biosensing Techniques / instrumentation*
  • Electrodes
  • Odorants / analysis*
  • Onions / chemistry*
  • Oxazines
  • Pediococcus / enzymology
  • Pyruvate Oxidase
  • Pyruvic Acid / analysis*

Substances

  • Oxazines
  • Meldola blue
  • Pyruvic Acid
  • Pyruvate Oxidase