Previous studies have shown that a decrease in muscle tension is not proportional to decrease in the ATP concentration and free energy for ATP degradation but is proportional to the decrease in ATP consumption during muscle contraction, and that the free ADP concentration in the cell can be estimated using the Pi/PCr ratio obtained by 31P NMR. From this view, we discuss findings on muscle energetics during exercise that have been clarified by 31P NMR and its future problems.