Solid-state NMR spectroscopy of anionic framework aluminophosphates: a new method to determine the al/p ratio

Dan Zhou; Jun Xu; Jihong Yu; Lei Chen; Feng Deng; Ruren Xu

doi:10.1021/jp056335q

Solid-state NMR spectroscopy of anionic framework aluminophosphates: a new method to determine the al/p ratio

J Phys Chem B. 2006 Feb 9;110(5):2131-7. doi: 10.1021/jp056335q.

Authors

Dan Zhou¹, Jun Xu, Jihong Yu, Lei Chen, Feng Deng, Ruren Xu

Affiliation

¹ State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China.

PMID: 16471794
DOI: 10.1021/jp056335q

Abstract

A series of anionic framework aluminophosphates, with different Al/P ratios, have been investigated by various solid-state NMR techniques, including 27Al, 31P magic angle spinning (MAS), 27Al-->31P cross polarization (CP), 27Al{31P} rotational echo double resonance (REDOR), and 31P{27Al} transfer of population double resonance (TRAPDOR). Different Al coordinations (AlO4b, AlO5b, and AlO6b) and P coordinations (PO4b, PO3bOt, PO2bO2t, and PObO3t), where b represents bridging oxygens and t represents terminal oxygens, can be unambiguously determined based on the solid-state NMR spectroscopy. Furthermore, a new method to determine the Al/P ratio of open-framework aluminophosphates has been established, which is useful for the understanding of unknown aluminophosphate structures.