Four gene products are required for the fungal synthesis of the indole-diterpene, paspaline

FEBS Lett. 2006 Mar 6;580(6):1625-30. doi: 10.1016/j.febslet.2006.02.008. Epub 2006 Feb 17.

Abstract

Paspaline belongs to a large, structurally and functionally diverse group of indole-diterpenes synthesized by filamentous fungi. However, the identity of the gene products required for the biosynthesis of paspaline, a key intermediate for the synthesis of paxilline and other indole-diterpenes, is not known. Transfer of constructs containing different pax gene combinations into a paxilline negative deletion derivative of Penicillium paxilli demonstrated that just four proteins, PaxG, a geranylgeranyl diphosphate synthase, PaxM, a FAD-dependent monooxygenase, PaxB, a putative membrane protein, and PaxC, a prenyl transferase, are required for the biosynthesis of paspaline.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Dimethylallyltranstransferase / genetics
  • Diterpenes / metabolism*
  • Farnesyltranstransferase / genetics
  • Fungal Proteins / genetics*
  • Gene Deletion
  • Genes, Fungal
  • Indoles / metabolism*
  • Membrane Proteins / genetics
  • Oxygenases / genetics
  • Penicillium / genetics
  • Penicillium / metabolism*

Substances

  • Diterpenes
  • Fungal Proteins
  • Indoles
  • Membrane Proteins
  • paspaline
  • Oxygenases
  • dimethylaniline monooxygenase (N-oxide forming)
  • Dimethylallyltranstransferase
  • Farnesyltranstransferase