Unidirectional electronic ring current driven by a few cycle circularly polarized laser pulse: quantum model simulations for Mg-porphyrin

Ingo Barth; Jörn Manz; Yasuteru Shigeta; Kiyoshi Yagi

doi:10.1021/ja057197l

Unidirectional electronic ring current driven by a few cycle circularly polarized laser pulse: quantum model simulations for Mg-porphyrin

J Am Chem Soc. 2006 May 31;128(21):7043-9. doi: 10.1021/ja057197l.

Authors

Ingo Barth¹, Jörn Manz, Yasuteru Shigeta, Kiyoshi Yagi

Affiliation

¹ Institut für Chemie und Biochemie, Freie Universität Berlin, Takustrasse 3, 14195 Berlin, Germany.

PMID: 16719485
DOI: 10.1021/ja057197l

Abstract

A circularly polarized ultraviolet (UV) laser pulse may excite a unidirectional valence-type electronic ring current in an oriented molecule, within the pulse duration of a few femtoseconds (e.g., tau = 3.5 fs). The mechanism is demonstrated by quantum model simulation for |X = |1(1)A(1g) --> |E(+) = |4 (1)E(u+) population transfer in the model system, Mg-porphyrin. The net ring current generated by the laser pulse (I = 84.5 microA) is at least 100 times stronger than any ring current, which could be induced by means of permanent magnetic fields, with present technology.