Thermal decomposition of commercial silicone oil to produce high yield high surface area SiC nanorods

J Phys Chem B. 2006 Jun 15;110(23):11237-40. doi: 10.1021/jp061407e.

Abstract

This article reports on the synthesis of high surface area (563m2/g) beta-SiC nanorods by thermal decomposition of commercial silicone oil at a relatively low reaction temperature (800 degrees C) in a closed Swagelok cell. High yield (75%) of SiC nanorods are obtained in this one-stage, solvent-, catalyst-, and template-free synthesis technique that runs at a relative low temperature and employs cheap single-precursor. The morphological (TEM, HR-SEM), compositional (CHNS, EDX, SAEDX]), structural (XRD, HR-TEM, and ED), thermal (TGA) characterizations and surface area analysis are carried out for the obtained SiC nanorods. The possibility of hydrogen storage in this high surface area nano-SiC rods are also tested and reported for the first time.

MeSH terms

  • Carbon Compounds, Inorganic / chemistry*
  • Microscopy, Electron, Scanning
  • Microscopy, Electron, Transmission
  • Nanotubes*
  • Silicon Compounds / chemistry*
  • Silicone Oils / chemistry*
  • X-Ray Diffraction

Substances

  • Carbon Compounds, Inorganic
  • Silicon Compounds
  • Silicone Oils
  • silicon carbide